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Why scientists are making transparent wood

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a transparent piece of wood on top of a green leaf

Enlarge / See-through wood has a number of interesting properties that researchers hope to exploit. (credit: WILEY‐VCH VERLAG GMBH & CO. KGAA, WEINHEIM)

Thirty years ago, a botanist in Germany had a simple wish: to see the inner workings of woody plants without dissecting them. By bleaching away the pigments in plant cells, Siegfried Fink managed to create transparent wood, and he published his technique in a niche wood technology journal. The 1992 paper remained the last word on see-through wood for more than a decade, until a researcher named Lars Berglund stumbled across it.

Berglund was inspired by Fink’s discovery, but not for botanical reasons. The materials scientist, who works at KTH Royal Institute of Technology in Sweden, specializes in polymer composites and was interested in creating a more robust alternative to transparent plastic. And he wasn’t the only one interested in wood’s virtues. Across the ocean, researchers at the University of Maryland were busy on a related goal: harnessing the strength of wood for nontraditional purposes.

Now, after years of experiments, the research of these groups is starting to bear fruit. Transparent wood could soon find uses in super-strong screens for smartphones; in soft, glowing light fixtures; and even as structural features, such as color-changing windows.

“I truly believe this material has a promising future,” says Qiliang Fu, a wood nanotechnologist at Nanjing Forestry University in China who worked in Berglund’s lab as a graduate student.

Wood is made up of countless little vertical channels, like a tight bundle of straws bound together with glue. These tube-shaped cells transport water and nutrients throughout a tree, and when the tree is harvested and the moisture evaporates, pockets of air are left behind. To create see-through wood, scientists first need to modify or get rid of the glue, called lignin, that holds the cell bundles together and provides trunks and branches with most of their earthy brown hues. After bleaching lignin’s color away or otherwise removing it, a milky-white skeleton of hollow cells remains.

This skeleton is still opaque, because the cell walls bend light to a different degree than the air in the cell pockets does—a value called a refractive index. Filling the air pockets with a substance like epoxy resin that bends light to a similar degree to the cell walls renders the wood transparent.

The material the scientists worked with is thin—typically less than a millimeter to around a centimeter thick. But the cells create a sturdy honeycomb structure, and the tiny wood fibers are stronger than the best carbon fibers, says materials scientist Liangbing Hu, who leads the research group working on transparent wood at the University of Maryland in College Park. And with the resin added, transparent wood outperforms plastic and glass: In tests measuring how easily materials fracture or break under pressure, transparent wood came out around three times stronger than transparent plastics like Plexiglass and about 10 times tougher than glass.

“The results are amazing, that a piece of wood can be as strong as glass,” says Hu, who highlighted the features of transparent wood in the 2023 Annual Review of Materials Research.

The process also works with thicker wood but the view through that substance is hazier because it scatters more light. In their original studies from 2016, Hu and Berglund both found that millimeter-thin sheets of the resin-filled wood skeletons let through 80 to 90 percent of light. As the thickness gets closer to a centimeter, light transmittance drops: Berglund’s group reported that 3.7-millimeter-thick wood—roughly two pennies thick—transmitted only 40 percent of light.

The slim profile and strength of the material means it could be a great alternative to products made from thin, easily shattered cuts of plastic or glass, such as display screens. The French company Woodoo, for example, uses a similar lignin-removing process in its wood screens, but leaves a bit of lignin to create a different color aesthetic. The company is tailoring its recyclable, touch-sensitive digital displays for products, including car dashboards and advertising billboards.

But most research has centered on transparent wood as an architectural feature, with windows a particularly promising use, says Prodyut Dhar, a biochemical engineer at the Indian Institute of Technology Varanasi. Transparent wood is a far better insulator than glass, so it could help buildings retain heat or keep it out. Hu and colleagues have also used polyvinyl alcohol, or PVA—a polymer used in glue and food packaging—to infiltrate the wood skeletons, making transparent wood that conducts heat at a rate five times lower than that of glass, the team reported in 2019 in Advanced Functional Materials.

And researchers are coming up with other tweaks to increase wood’s ability to hold or release heat, which would be useful for energy-efficient buildings. Céline Montanari, a materials scientist at RISE Research Institutes of Sweden, and colleagues experimented with phase-change materials, which flip from storing to releasing heat when they change from solid to liquid, or vice-versa. By incorporating polyethylene glycol, for example, the scientists found that their wood could store heat when it was warm and release heat as it cooled, work they published in ACS Applied Materials and Interfaces In 2019.

Transparent wood windows would therefore be stronger and aid in temperature control better than traditional glass, but the view through them would be hazy, more similar to frosted glass than a regular window. However, the haziness could be an advantage if users want diffuse light: Since thicker wood is strong, it could be a partially load-bearing light source, Berglund says, potentially acting as a ceiling that provides soft, ambient light to a room.

Hu and Berglund have continued to toy with ways to bestow new properties on transparent wood. Around five years ago, Berglund and colleagues at KTH and Georgia Institute of Technology found they could mimic smart windows, which can switch from transparent to tinted to block visibility or the Sun’s rays. The researchers sandwiched an electrochromic polymer—a substance that can change color with electricity—between layers of transparent wood coated with an electrode polymer to conduct electricity. This created a pane of wood that changes from clear to magenta when users run a small electrical current through it.

More recently, the two groups have shifted their attention to improving the sustainability of transparent wood production. For example, the resin used to fill the wood scaffolding is typically a petroleum-derived plastic product, so it’s better to avoid using it, Montanari says. As a replacement, she and colleagues invented a fully bio-based polymer derived from citrus peels. The team first combined acrylic acid and limonene, a chemical extracted from lemon and orange rinds that’s found in essential oils. Then they impregnated delignified wood with it. Even with a fruity filling, the bio-based transparent wood maintained its mechanical and optical properties, withstanding around 30 megapascals of pressure more than regular wood and transmitting around 90 percent of light, the researchers reported in 2021 in Advanced Science.

Hu’s lab, meanwhile, recently reported in Science Advances a greener lignin-bleaching method that leans on hydrogen peroxide and UV radiation, further reducing the energy demands of production. The team brushed wood slices ranging from about 0.5 to 3.5 millimeters in thickness with hydrogen peroxide, then left them in front of UV lamps to mimic the Sun’s rays. The UV bleached away the pigment-containing parts of lignin but left the structural parts intact, thus helping to retain more strength in the wood.

These more environmentally friendly approaches help limit the amount of toxic chemicals and fossil-based polymers used in production, but for now, glass still has lower end-of-life environmental impacts than transparent wood, according to an analysis by Dhar and colleagues in Science of the Total Environment. Embracing greener production schemes and scaling up manufacturing are two steps necessary to add transparent wood to mainstream markets, researchers say, but it will take time. However, they are confident it can be done and believe in its potential as a sustainable material.

“When you’re trying to achieve sustainability, you don’t only want to match the properties of fossil-based materials,” Montanari says. “As a scientist, I want to surpass this.”

Jude Coleman is an Oregon-based freelance journalist who covers ecology, climate change, and the environment. Read more of her work at judecoleman.com. This article originally appeared in Knowable Magazine, an independent journalistic endeavor from Annual Reviews. Sign up for the newsletter.

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teh_g
4 hours ago
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23andMe changes arbitration terms after hack impacting millions

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23andMe changes arbitration terms after hack impacting millions

Enlarge (credit: Bloomberg / Contributor | Bloomberg)

Shortly after 23andMe confirmed that hackers stole ancestry data of 6.9 million users, 23andMe has updated its terms of service, seemingly cutting off a path previously granted to users seeking public accountability when resolving disputes.

According to a post on Hacker News, the "23andMe Team" notified users in an email that "important updates were made to the Dispute Resolution and Arbitration section" of 23andMe's terms of service on November 30. This was done, 23andMe told users, "to include procedures that will encourage a prompt resolution of any disputes and to streamline arbitration proceedings where multiple similar claims are filed."

In the email, 23andMe told users that they had 30 days to notify the ancestry site that they disagree with the new terms. Otherwise, 23andMe users "will be deemed to have agreed to the new terms." The process for opting out is detailed in the site's ToS, instructing users to send written notice of their decision to opt out in an email to arbitrationoptout@23andme.com.

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teh_g
3 days ago
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So who wants to start some mass arbitration?
Roseville, CA
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petrilli
3 days ago
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Scum
Arlington, VA

Report: Amazon made $1B with secret algorithm for spiking prices Internet-wide

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Report: Amazon made $1B with secret algorithm for spiking prices Internet-wide

Enlarge (credit: Bloomberg / Contributor | Bloomberg)

Last week, the Federal Trade Commission sued Amazon, alleging that the online retailer was illegally maintaining a monopoly. Much of the FTC's complaint against Amazon was redacted, but The Wall Street Journal yesterday revealed key details obscured in the complaint regarding a secret algorithm. The FTC alleged that Amazon once used the algorithm to raise prices across the most popular online shopping destinations.

People familiar with the FTC's allegations in the complaint told the Journal that it all started when Amazon developed an algorithm code-named "Project Nessie." It allegedly works by manipulating rivals' weaker pricing algorithms and locking competitors into higher prices. The controversial algorithm was allegedly used for years and helped Amazon to "improve its profits on items across shopping categories" and "led competitors to raise their prices and charge customers more," the WSJ reported.

The FTC's complaint said:

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teh_g
66 days ago
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Roseville, CA
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Don’t be a Statistic

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The post Don’t be a Statistic appeared first on The Perry Bible Fellowship.

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teh_g
86 days ago
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popbobmob
86 days ago
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lolcsi

Saturday Morning Breakfast Cereal - 63

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Click here to go see the bonus panel!

Hovertext:
Unfortunately, it turns out many of them are just corporate accounts looking to self grief-related products.


Today's News:
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teh_g
448 days ago
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Inflating spider corpse creates robotic claw game of nightmares

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(credit: Preston Innovation Laboratory)

Shortly after the Preston Innovation Lab was set up at Rice University, graduate student Faye Yap was rearranging a few things when she noticed a dead curled-up spider in the hallway. Curious about why spiders curl up when they die, she did a quick search to find the answer. And that answer—essentially, internal hydraulics—led to delightfully morbid inspiration: Why not use the bodies of dead spiders as tiny air-powered grippers for picking up and maneuvering tiny electronic parts?

Yap and her colleagues—including adviser Daniel Preston—did just that. They transformed a dead wolf spider into a gripping tool with just a single assembly step—essentially launching a novel new research area they have cheekily dubbed "necrobotics." They outlined the process in detail in a new paper published in the journal Advanced Science. The authors suggest the gripper could be ideal for delicate "pick-and-place" repetitive tasks and could possibly be used one day in the assembly of microelectronics.

Preston's lab specializes in so-called soft robotics, which eschews the usual hard plastics, metals, and electronics in favor of more nontraditional materials. Hydrogels and elastomers, for example, can serve as actuators powered by chemical reactions, pneumatics, or even light. Roboticists have also long found inspiration for their designs in nature, studying the locomotion of such animals as cheetahs, snakes, insects, starfish, jellyfish, and octopuses. (See, for example, our story on the development of the OctaGlove, designed to grip slippery objects underwater.)

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teh_g
498 days ago
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This is a case where science has gone too far.
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